Chloropentammineplatinum chloride

Chloropentammineplatinum chloride
Names
	Other names Pentammineplatinum(IV) chloride, Pentammineplatinum chloride, Chloropentammineplatinum(IV) chloride
Identifiers
CAS Number	16893-11-1;
3D model (JSmol)	Interactive image;
ChemSpider	141606;
PubChem CID	161201;
CompTox Dashboard (EPA)	DTXSID20937566 ;
	InChI InChI=1S/4ClH.5H3N.Pt/h41H;51H3;/q;;;;;;;;;+4/p-4 Key: XXWVYPODEOCLBT-UHFFFAOYSA-J;
	SMILES N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Cl-].[Pt+4];
Properties
Chemical formula	Cl4H15N5Pt
Molar mass	422.04 g·mol−1
Appearance	white solid
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Chloropentammineplatinum chloride is an inorganic compound with the formula [PtCl(NH₃)₅]Cl₃. It is a chloride salt of the coordination complex [PtCl(NH₃)₅]⁺. It is a white, water soluble solid.

The compound is prepared by treating potassium hexachloroplatinate with aqueous ammonia:^[1]

K₂PtCl₆ + 5 NH₃ → [PtCl(NH₃)₅]Cl₃ + 2 KCl

Related platinum(IV) ammines

The title complex is one of several platinum ammine complexes.

Hexaammineplatinum(IV) chloride
Trichlorotriammineplatinum(IV) chloride^[2]
cis-Tetrachlorodiammineplatinum(IV)^[3]
trans-Tetrachlorodiammineplatinum(IV) (RN 16986-23-5)^[3]

References

^ Curtis, Neville J.; Lawrance, Geoffrey A.; Sargeson, Alan M.; Johnson, Ronald C. (1986). "Pentaammineplatinum(IV) Complexes". Inorganic Syntheses. Vol. 24. pp. 277–279. doi:10.1002/9780470132555.ch74. ISBN 9780471834410.
^ Gildengershel, Kh. I. (1966). "Synthesis of Cleve's salts [Pt(NH₃)₃Cl]Cl and [Pt(NH₃)₃Cl₃]Cl". Zhurnal Prikladnoi Khimii. 39: 223-5.
^ ^a ^b Kauffman, George B.; Slusarczuk, George; Kirschner, Stanley (1963). "cis ‐ and trans ‐Tetrachlorodiammineplatinum(IV)". Inorganic Syntheses. Vol. 7. pp. 236–238. doi:10.1002/9780470132388.ch62. ISBN 9780470131664.

[1] Curtis, Neville J.; Lawrance, Geoffrey A.; Sargeson, Alan M.; Johnson, Ronald C. (1986). "Pentaammineplatinum(IV) Complexes". Inorganic Syntheses. Vol. 24. pp. 277–279. doi:10.1002/9780470132555.ch74. ISBN 9780471834410.

[2] Gildengershel, Kh. I. (1966). "Synthesis of Cleve's salts [Pt(NH₃)₃Cl]Cl and [Pt(NH₃)₃Cl₃]Cl". Zhurnal Prikladnoi Khimii. 39: 223-5.

[GBK-3] Kauffman, George B.; Slusarczuk, George; Kirschner, Stanley (1963). "cis ‐ and trans ‐Tetrachlorodiammineplatinum(IV)". Inorganic Syntheses. Vol. 7. pp. 236–238. doi:10.1002/9780470132388.ch62. ISBN 9780470131664.

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