Hydrotelluride

Hydrotelluride
Names
	Other names tellanide
Identifiers
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:30460;
ChemSpider	19241428;
Gmelin Reference	1407875
	InChI InChI=1S/H2Te/h1H2/p-1; Key: VTLHPSMQDDEFRU-UHFFFAOYSA-M;
	SMILES [Te-][H];
Properties
Chemical formula	HTe−
Molar mass	128.61 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

A hydrotelluride or tellanide is an ion or a chemical compound containing the [HTe]⁻ anion which has a hydrogen atom connected to a tellurium atom. HTe is a pseudohalogen. Organic compounds containing the -TeH group are called tellurols. "Tellanide" is the IUPAC name from the Red Book, but hydrogen(tellanide)(1−) is also listed. "Tellanido" as a ligand is not named, however ditellanido is used for HTeTe⁻.^[1]

Hydrotellurides are usually unstable at room temperature.^[2]

List

	formula	system	space group	unit cell Å	density	comment	reference
ammonium hydrotelluride	NH₄TeH					at 25°C pressure = 22.7 mmHg, decomposing to H₃N and H₂Te then to Te and H₂	^[3]
ethylmethylimidazolinium hydrotelluride	[(C₂H₅)(CH₃)C₃N₂H₂]⁺TeH⁻						^[2]
N-butyl-N-methylpyrollidinium hydrotelluride	[(C₄H₉)(CH₃)C₄NH₈]⁺TeH⁻					decompose at room temperature over a fortnight; decompose 116°C	^[2]
sodium hydrotelluride	NaTeH						^[4]
tri-n-butyl-methylphosphonium hydrotelluride	[(C₄H₉)₃(CH₃)P]⁺TeH⁻					red; decompose 163°C	^[2]
tetraphenylphosphonium hydrotelluride	Ph₄PTeH						^[5]
	[(C₅H₅)Co]₂(μ-P(CH₃)₂)₂(μ-TeH)•PF₆					red-brown	^[6]
	Na[(CO)₅Cr(TeH)]						^[7]^[8]
	[(Ph₃P)₂N]⁺[(CO)₅Cr(TeH)]⁻						^[8]
	[(Ph₃P)₂N]⁺[(CO)₅Cr(TeH)Cr(CO)₅]⁻						^[7]^[8]
	[CpCr(CO)₃]₂(μ-TeH)						^[7]
	[(CO)₄Mn(TeH)]₂						^[7]^[9]
Cp*=C₅Me₅	Cp*₂Zr(TeH){η¹-OC(Ph)=CH₂}						^[7]
	(t-BuC₅H₄)₂Nb(η²-Te₂)H					dark orange	^[10]
	(η-C₅H₄Me)Ru(PPh₃)₂(TeH)						^[11]
	(CH₂CH₂PPh₂)₃PRhTeH	hexagonal	P6₃	a=13.542 c=12.346 Z=2		cherry red; decomposed by light	^[12]^[5]
	(CH₂CH₂PPh₂)₃PRh(TeH)(H)CF₃SO₃						^[12]
	(MeCp)₂Ta(TeH)CO						^[13]
	(MeCp)₂Ta(TeH) (η²-COTe)						^[13]
	Na[(CO)₅W(TeH)]						^[7]^[8]
	Ph₄As[(CO)₅W(TeH)]						^[8]
	Ph₄As[(CO)₅W(TeH)W(CO)₅]						^[7]^[8]
	Cp*Re(CO)₂(H)(TeH)	monoclinic	P2₁/m	a=7.467 b=13.208 c=7.570 β=99.48° Z=2	2.287	red-brown	^[14]^[15]^[7]
(^AdArO)₃N³⁻ = tris(2-hydroxy-3-adamantyl-5-methylbenzyl)amine)	[((^AdArO)₃N)U(CH₃OC₂H₄OCH₃)(TeH)]					stable to 80°C; U–Te bond length 3.122 Å	^[16]
	{((^AdArO)₃N)U}₂(μ-TeH)₂						^[16]

References

^ . For the group -HTe or radical HTe^• the term tellanyl is used.Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005 (PDF). p. 304.
^ ^a ^b ^c ^d Finger, Lars H.; Sundermeyer, Jörg (2016-03-14). "Halide-Free Synthesis of Hydrochalcogenide Ionic Liquids of the Type [Cation][HE] (E=S, Se, Te)". Chemistry – A European Journal. 22 (12): 4218–4230. doi:10.1002/chem.201504577. ISSN 0947-6539. PMID 26879604.
^ Mikus, F. F.; Carlyon, S. J. (May 1950). "The Equilibrium between Ammonia and Hydrogen Telluride 1". Journal of the American Chemical Society. 72 (5): 2295–2296. doi:10.1021/ja01161a522. ISSN 0002-7863.
^ "The Structure of Yttrium Hydride Telluride YHTe from Single-Crystal X-Ray Diffraction Data". Joint Polish-German Crystallographic Meeting, February 24–27, 2020, Wrocław, Poland: 64–65. 24 February 2020. doi:10.1515/9783110692914-002.
^ ^a ^b Roof, Lisa C.; Kolis, Joseph W. (1993-05-01). "New developments in the coordination chemistry of inorganic selenide and telluride ligands". Chemical Reviews. 93 (3): 1037–1080. doi:10.1021/cr00019a010. ISSN 0009-2665.
^ Hofmann, Werner; Werner, Helmut (December 1981). "Electrophilic Addition of a Sulfur, Selenium, and Tellurium Atom as well as of an SO 2 Molecule to a Metal-Metal Bond". Angewandte Chemie International Edition in English. 20 (12): 1014–1016. doi:10.1002/anie.198110142. ISSN 0570-0833.
^ ^a ^b ^c ^d ^e ^f ^g ^h Howard, William A.; Parkin, Gerard (January 1994). "Terminal oxo, sulfido, selenido, and tellurido complexes of zirconium, (.eta.5-C5Me4R)2Zr(E)(NC5H5): comparison of terminal Zr-E single and Zr:E double-bond lengths". Journal of the American Chemical Society. 116 (2): 606–615. doi:10.1021/ja00081a022. ISSN 0002-7863.
^ ^a ^b ^c ^d ^e ^f Hausmann, Heinz; Höfler, Mathias; Kruck, Thomas; Zimmermann, Heinz Willi (March 1981). "Chalkogenide als Komplexliganden, I. Carbonyl-Hydrogenchalkogenid-Komplexe von Chrom, Molybdän und Wolfram". Chemische Berichte. 114 (3): 975–981. doi:10.1002/cber.19811140315. ISSN 0009-2940.
^ Küllmer, Volker; Vahrenkamp, Heinrich (January 1977). "Selen- und Tellur-verbrückte Carbonylkomplexe des Mangans und Rheniums". Chemische Berichte. 110 (1): 228–236. doi:10.1002/cber.19771100122. ISSN 0009-2940.
^ Ebner, Alexander; Meier, Walter; Mugnier, Yves; Wachter, Joachim (July 2007). "Investigation into the reaction of (t-BuC5H4)2Nb(η2-Te2)H with CH3Li: Hydride abstraction versus telluride methylation". Inorganica Chimica Acta. 360 (10): 3330–3334. doi:10.1016/j.ica.2007.03.060.
^ Schriver, D. F.; Bruce, M. I. (2002-09-10). Comprehensive Organometallic Chemistry II, Volume 7: Iron, Ruthenium and Osmium: A Review of the Literature 1982-1994. Elsevier. p. 883. ISBN 978-0-08-096396-9.
^ ^a ^b Di Vaira, Massimo; Peruzzini, Maurizio; Stoppioni, Piero (March 1991). "Hydrochalcogenide and hydride hydrochalcogenide derivatives of rhodium". Inorganic Chemistry. 30 (5): 1001–1007. doi:10.1021/ic00005a024. ISSN 0020-1669.
^ ^a ^b Winkler, Uwe; Khan, Masood A.; Nicholas, Kenneth M. (August 1998). "Atom addition and insertion reactions of (MeCp)2Ta(H)CO with sulfur, tellurium, carbonyl sulfide and carbon disulfide". Inorganic Chemistry Communications. 1 (8): 317–319. doi:10.1016/S1387-7003(98)00085-9.
^ Herrmann, Wolfgang A.; Hecht, Christian; Herdtweck, Eberhardt; Kneuper, Heinz-Josef (February 1987). "Oxidative Addition of Hydrogen Telluride to Organometallic Fragments". Angewandte Chemie International Edition in English. 26 (2): 132–134. doi:10.1002/anie.198701321. ISSN 0570-0833.
^ Fehlner, Thomas P. (1992), Fehlner, Thomas P. (ed.), "Main Group Fragments as Ligands to Transition Metals", Inorganometallic Chemistry, Boston, MA: Springer US, pp. 13–71, doi:10.1007/978-1-4899-2459-9_2, ISBN 978-1-4899-2461-2, retrieved 2024-05-23
^ ^a ^b Franke, Sebastian M.; Rosenzweig, Michael W.; Heinemann, Frank W.; Meyer, Karsten (2015). "Reactivity of uranium( iii ) with H 2 E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium( iv ) hydrochalcogenido complexes". Chemical Science. 6 (1): 275–282. doi:10.1039/C4SC02602K. ISSN 2041-6520. PMC 5811169. PMID 29560170.

[1] . For the group -HTe or radical HTe^• the term tellanyl is used.Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005 (PDF). p. 304.

[:0-2] Finger, Lars H.; Sundermeyer, Jörg (2016-03-14). "Halide-Free Synthesis of Hydrochalcogenide Ionic Liquids of the Type [Cation][HE] (E=S, Se, Te)". Chemistry – A European Journal. 22 (12): 4218–4230. doi:10.1002/chem.201504577. ISSN 0947-6539. PMID 26879604.

[3] Mikus, F. F.; Carlyon, S. J. (May 1950). "The Equilibrium between Ammonia and Hydrogen Telluride 1". Journal of the American Chemical Society. 72 (5): 2295–2296. doi:10.1021/ja01161a522. ISSN 0002-7863.

[4] "The Structure of Yttrium Hydride Telluride YHTe from Single-Crystal X-Ray Diffraction Data". Joint Polish-German Crystallographic Meeting, February 24–27, 2020, Wrocław, Poland: 64–65. 24 February 2020. doi:10.1515/9783110692914-002.

[:3-5] Roof, Lisa C.; Kolis, Joseph W. (1993-05-01). "New developments in the coordination chemistry of inorganic selenide and telluride ligands". Chemical Reviews. 93 (3): 1037–1080. doi:10.1021/cr00019a010. ISSN 0009-2665.

[6] Hofmann, Werner; Werner, Helmut (December 1981). "Electrophilic Addition of a Sulfur, Selenium, and Tellurium Atom as well as of an SO 2 Molecule to a Metal-Metal Bond". Angewandte Chemie International Edition in English. 20 (12): 1014–1016. doi:10.1002/anie.198110142. ISSN 0570-0833.

[:5-7] ^ ^a ^b ^c ^d ^e ^f ^g ^h Howard, William A.; Parkin, Gerard (January 1994). "Terminal oxo, sulfido, selenido, and tellurido complexes of zirconium, (.eta.5-C5Me4R)2Zr(E)(NC5H5): comparison of terminal Zr-E single and Zr:E double-bond lengths". Journal of the American Chemical Society. 116 (2): 606–615. doi:10.1021/ja00081a022. ISSN 0002-7863.

[:6-8] ^ ^a ^b ^c ^d ^e ^f Hausmann, Heinz; Höfler, Mathias; Kruck, Thomas; Zimmermann, Heinz Willi (March 1981). "Chalkogenide als Komplexliganden, I. Carbonyl-Hydrogenchalkogenid-Komplexe von Chrom, Molybdän und Wolfram". Chemische Berichte. 114 (3): 975–981. doi:10.1002/cber.19811140315. ISSN 0009-2940.

[9] Küllmer, Volker; Vahrenkamp, Heinrich (January 1977). "Selen- und Tellur-verbrückte Carbonylkomplexe des Mangans und Rheniums". Chemische Berichte. 110 (1): 228–236. doi:10.1002/cber.19771100122. ISSN 0009-2940.

[10] Ebner, Alexander; Meier, Walter; Mugnier, Yves; Wachter, Joachim (July 2007). "Investigation into the reaction of (t-BuC5H4)2Nb(η2-Te2)H with CH3Li: Hydride abstraction versus telluride methylation". Inorganica Chimica Acta. 360 (10): 3330–3334. doi:10.1016/j.ica.2007.03.060.

[11] Schriver, D. F.; Bruce, M. I. (2002-09-10). Comprehensive Organometallic Chemistry II, Volume 7: Iron, Ruthenium and Osmium: A Review of the Literature 1982-1994. Elsevier. p. 883. ISBN 978-0-08-096396-9.

[:2-12] Di Vaira, Massimo; Peruzzini, Maurizio; Stoppioni, Piero (March 1991). "Hydrochalcogenide and hydride hydrochalcogenide derivatives of rhodium". Inorganic Chemistry. 30 (5): 1001–1007. doi:10.1021/ic00005a024. ISSN 0020-1669.

[:4-13] Winkler, Uwe; Khan, Masood A.; Nicholas, Kenneth M. (August 1998). "Atom addition and insertion reactions of (MeCp)2Ta(H)CO with sulfur, tellurium, carbonyl sulfide and carbon disulfide". Inorganic Chemistry Communications. 1 (8): 317–319. doi:10.1016/S1387-7003(98)00085-9.

[14] Herrmann, Wolfgang A.; Hecht, Christian; Herdtweck, Eberhardt; Kneuper, Heinz-Josef (February 1987). "Oxidative Addition of Hydrogen Telluride to Organometallic Fragments". Angewandte Chemie International Edition in English. 26 (2): 132–134. doi:10.1002/anie.198701321. ISSN 0570-0833.

[15] Fehlner, Thomas P. (1992), Fehlner, Thomas P. (ed.), "Main Group Fragments as Ligands to Transition Metals", Inorganometallic Chemistry, Boston, MA: Springer US, pp. 13–71, doi:10.1007/978-1-4899-2459-9_2, ISBN 978-1-4899-2461-2, retrieved 2024-05-23

[:1-16] Franke, Sebastian M.; Rosenzweig, Michael W.; Heinemann, Frank W.; Meyer, Karsten (2015). "Reactivity of uranium( iii ) with H 2 E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium( iv ) hydrochalcogenido complexes". Chemical Science. 6 (1): 275–282. doi:10.1039/C4SC02602K. ISSN 2041-6520. PMC 5811169. PMID 29560170.

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