Diruthenium tetraacetate chloride
4Cl.svg)
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| Names | |
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| IUPAC name
Ruthenium(II,III) acetate chloride
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| Other names
Tetrakis(mu-(acetato-O:O'))chlorodiruthenium
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
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PubChem CID
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| Properties | |
| C8H12ClO8Ru2 | |
| Molar mass | 473.77 g·mol−1 |
| Appearance | red-brown solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Diruthenium tetraacetate chloride is the coordination polymer with the formula {[Ru2(O2CCH3)4]Cl}n. A red brown solid, the compound is obtained by the reduction of ruthenium trichloride in acetic acid.[1] The compound has attracted much academic interest because it features a fractional metal-metal bond order of 2.5.[2]
The [Ru2(O2CCH3)4]+ core adopts the Chinese lantern structure, with four acetate ligands spanning the Ru2 center. The Ru-Ru distance is 228 pm.[3][4] The [Ru2(O2CCH3)4]+ units are linked by bridging chloride ligands.
References
[edit]- ^ Mitchell, Robert W.; Spencer, Alwyn; Wilkinson, Geoffrey (1973). "Carboxylato-Triphenylphosphine complexes of Ruthenium, Cationic Triphenylphosphine Complexes Derived from Them, and Their Behaviour as homogeneous hydrogenation Catalysts for Alkenes". Journal of the Chemical Society, Dalton Transactions (8): 846. doi:10.1039/DT9730000846.
- ^ Aquino, Manuel A.S. (1998). "Diruthenium and Diosmium Tetracarboxylates: Synthesis, Physical Properties and Applications". Coordination Chemistry Reviews. 170: 141–202. doi:10.1016/S0010-8545(97)00079-9.
- ^ Cotton, F.Albert; Kim, Youngmee; Ren, Tong (1993). "Molecular Structure and Magnetic Properties of a Linear Chain Compound, Ru2(O2CCMePh2)4Cl". Polyhedron. 12 (6): 607–611. doi:10.1016/S0277-5387(00)84975-X.
- ^ Martin, Don S.; Newman, Robert A.; Vlasnik, Lynn M. (1980). "Crystal structure and polarized electronic spectra for diruthenium tetraacetate chloride". Inorganic Chemistry. 19 (11): 3404–3407. doi:10.1021/ic50213a038. ISSN 0020-1669.